Dery, H., Dalal, P., Cywinski, L. & Sham, L. J. Spin-based logic in semiconductors for reconfigurable large-scale circuits. Nature 447, 573–576 (2007).
Vincent, R., Klyatskaya, S., Ruben, M., Wernsdorfer, W. & Balestro, F. Electronic read-out of a single nuclear spin using a molecular spin transistor. Nature 488, 357–360 (2012).
Baek, S. H. C. et al. Complementary logic operation based on electric-field controlled spin-orbit torques. Nat. Electron. 1, 398–403 (2018).
Fert, A., Reyren, N. & Cros, V. Magnetic skyrmions: advances in physics and potential applications. Nat. Rev. Mater. 2, 17031 (2017).
Gehring, P., Thijssen, J. M. & van der Zant, H. S. J. Single-molecule quantum-transport phenomena in break junctions. Nat. Rev. Phys. 1, 381–396 (2019).
Berciu, M., Rappoport, T. G. & Janko, B. Manipulating spin and charge in magnetic semiconductors using superconducting vortices. Nature 435, 71–75 (2005).
Bracher, T. et al. Detection of short-waved spin waves in individual microscopic spin-wave waveguides using the inverse spin hall effect. Nano Lett. 17, 7234–7241 (2017).
Tong, M. et al. Light-driven spintronic heterostructures for coded terahertz emission. ACS Nano 16, 8294–8300 (2022).
Simao, C. et al. A robust molecular platform for non-volatile memory devices with optical and magnetic responses. Nat. Chem. 3, 359–364 (2011).
Warner, M. et al. Potential for spin-based information processing in a thin-film molecular semiconductor. Nature 503, 504–508 (2013).
Lombardi, F. et al. Quantum units from the topological engineering of molecular graphenoids. Science 366, 1107–1110 (2019).
Abe, M. Diradicals. Chem. Rev. 113, 7011–7088 (2013).
Zeng, Z. et al. Pro-aromatic and anti-aromatic pi-conjugated molecules: an irresistible wish to be diradicals. Chem. Soc. Rev. 44, 6578–6596 (2015).
Naghibi, S. et al. Redox-addressable single-molecule junctions incorporating a persistent organic radical. Angew. Chem. Int. Ed. 61, e202116985 (2022).
Bejarano, F. et al. Robust organic radical molecular junctions using acetylene terminated groups for C–Au bond formation. J. Am. Chem. Soc. 140, 1691–1696 (2018).
Zhang, X. et al. Electron spin resonance of single iron phthalocyanine molecules and role of their non-localized spins in magnetic interactions. Nat. Chem. 14, 59–65 (2021).
Shen, Y. et al. Normal & reversed spin mobility in a diradical by electron-vibration coupling. Nat. Commun. 12, 6262 (2021).
Patera, L. L. et al. Resolving the unpaired-electron orbital distribution in a stable organic radical by Kondo resonance mapping. Angew. Chem. Int. Ed. 58, 11063–11067 (2019).
Baum, T. Y., Andez, S. F., Pena, D. G. & van der Zant, H. S. J. Magnetic fingerprints in an all-organic radical molecular break junction. Nano Lett. 22, 8086–8092 (2022).
Hayakawa, R. et al. Large magnetoresistance in single-radical molecular junctions. Nano Lett. 16, 4960–4967 (2016).
Mitra, G. et al. Interplay between magnetoresistance and Kondo resonance in radical single-molecule junctions. Nano Lett. 22, 5773–5779 (2022).
Pyurbeeva, E. et al. Controlling the entropy of a single-molecule junction. Nano Lett. 21, 9715–9719 (2021).
Pyurbeeva, E. & Mol, J. A. A thermodynamic approach to measuring entropy in a few-electron nanodevice. Entropy 23, 640 (2021).
Bajaj, A., Khurana, R. & Ali, M. E. Quantum interference and spin filtering effects in photo-responsive single molecule devices. J. Mater. Chem. C 9, 11242–11251 (2021).
Han, Y. et al. Electric-field-driven dual-functional molecular switches in tunnel junctions. Nat. Mater. 19, 843–848 (2020).
Fock, J. et al. Manipulation of organic polyradicals in a single-molecule transistor. Phys. Rev. B 86, 235403 (2012).
Li, L. et al. Highly conducting single-molecule topological insulators based on mono- and di-radical cations. Nat. Chem. 14, 1061–1067 (2022).
Chen, Z. et al. Evolution of the electronic structure in open-shell donor–acceptor organic semiconductors. Nat. Commun. 12, 5889 (2021).
Li, Y., Li, L., Wu, Y. & Li, Y. A review on the origin of synthetic metal radical: singlet open-shell radical ground state? J. Phys. Chem. C 121, 8579–8588 (2017).
Chen, Z. et al. Aggregation-induced radical of donor–acceptor organic semiconductors. J. Phys. Chem. Lett. 12, 9783–9790 (2021).
Chen, Z., Li, Y. & Huang, F. Persistent and stable organic radicals: design, synthesis, and applications. Chem 7, 288–332 (2021).
Lörtscher, E. Wiring molecules into circuits. Nat. Nanotechnol. 8, 381–384 (2013).
Xin, N. et al. Concepts in the design and engineering of single-molecule electronic devices. Nat. Rev. Phys. 1, 211–230 (2019).
Jia, C. et al. Covalently bonded single-molecule junctions with stable and reversible photoswitched conductivity. Science 352, 1443–1445 (2016).
Meng, L. et al. Dual-gated single-molecule field-effect transistors beyond Moore’s law. Nat. Commun. 13, 1410 (2022).
Yang, C. et al. Complete deciphering of the dynamic stereostructures of a single aggregation-induced emission molecule. Matter 5, 1224–1234 (2022).
Xin, N. et al. Stereoelectronic effect-induced conductance switching in aromatic chain single-molecule junctions. Nano Lett. 17, 856–861 (2017).
Yang, C. et al. Unveiling the full reaction path of the Suzuki–Miyaura cross-coupling in a single-molecule junction. Nat. Nanotechnol. 16, 1214–1223 (2021).
Yang, C. et al. Electric field-catalyzed single-molecule Diels–Alder reaction dynamics. Sci. Adv. 7, eabf0689 (2021).
Cao, Y. et al. Building high-throughput molecular junctions using indented graphene point contacts. Angew. Chem. Int. Ed. 51, 12228–12232 (2012).
Yang, C., Yang, C., Guo, Y., Feng, J. & Guo, X. Graphene–molecule–graphene single-molecule junctions to detect electronic reactions at the molecular scale. Nat. Protoc. 18, 1958–1978 (2023).
Mol, J. A. et al. Graphene–porphyrin single-molecule transistors. Nanoscale 7, 13181–13185 (2015).
Gehring, P. et al. Field-effect control of graphene–fullerene thermoelectric nanodevices. Nano Lett. 17, 7055–7061 (2017).
Gehring, P. et al. Quantum interference in graphene nanoconstrictions. Nano Lett. 16, 4210–4216 (2016).
Hayashi, H. et al. Monoradicals and diradicals of dibenzofluoreno[3,2-b]fluorene isomers: mechanisms of electronic delocalization. J. Am. Chem. Soc. 142, 20444–20455 (2020).
Dressler, J. J. et al. Thiophene and its sulfur inhibit indenoindenodibenzothiophene diradicals from low-energy lying thermal triplets. Nat. Chem. 10, 1134–1140 (2018).
Qin, F., Auerbach, A. & Sachs, F. Estimating single-channel kinetic parameters from idealized patch clamp data containing missed events. Biophys. J. 70, 264–280 (1996).
Huang, X. et al. Electric field–induced selective catalysis of single-molecule reaction. Sci. Adv. 5, eaaw3072 (2019).
Frisch, M. J. et al. Gaussian16 Revision C.01 (Gaussian, 2016).
Yamaguchi, K. The electronic structures of biradicals in the unrestricted Hartree–Fock approximation. Chem. Phys. Lett. 33, 330–335 (1975).
Schleyer, P. V. R. et al. Dissected nucleus-independent chemical shift analysis of π-aromaticity and antiaromaticity. Org. Lett. 3, 2465–2468 (2001).
Neese, F. The ORCA program system. Wiley Interdiscip. Rev. Comput. Mol. Sci. 2, 73–78 (2012).
Grimme, S. & Hansen, A. A practicable real‐space measure and visualization of static electron correlation effects. Angew. Chem. Int. Ed. 54, 12308–12313 (2005).
Wang, M. et al. Donor-acceptor conjugated polymer based on naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole for high-performance polymer solar cells. J. Am. Chem. Soc. 133, 9638–9641 (2011).
Brandbyge, M., Mozos, J. L., Ordejón, P., Taylor, J. & Stokbro, K. Density-functional method for nonequilibrium electron transport. Phys. Rev. B 65, 165401 (2002).
Wang, B., Wang, J. & Guo, H. Current partition: a nonequilibrium Green’s function approach. Phys. Rev. Lett. 82, 398–401 (1999).
Taylor, J., Guo, H. & Wang, J. Ab initio modeling of quantum transport properties of molecular electronic devices. Phys. Rev. B 63, 245407 (2001).
Soler, J. M. et al. The SIESTA method for ab initio order-N materials simulations. J. Phys. Condens. Matter 14, 2745–2779 (2002).
Troullier, N. & Martins, J. A straightforward method for generating soft transferable pseudopotentials. Solid State Commun. 74, 613–616 (1990).
Heyd, J., Scuseria, G. E. & Ernzerhof, M. Hybrid functionals based on a screened coulomb potential. J. Chem. Phys. 118, 8207–8215 (2003).
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