Lopez, J., Mackanic, D. G., Cui, Y. & Bao, Z. Designing polymers for advanced battery chemistries. Nat. Rev. Mater. 4, 312–330 (2019).
Mindemark, J., Lacey, M. J., Bowden, T. & Brandell, D. Beyond PEO—alternative host materials for Li+-conducting solid polymer electrolytes. Prog. Polym. Sci. 81, 114–143 (2018).
Cui, G. Reasonable design of high-energy-density solid-state lithium-metal batteries. Matter 2, 805–815 (2020).
Yue, L. et al. All solid-state polymer electrolytes for high-performance lithium ion batteries. Energy Storage Mater. 5, 139–164 (2016).
Angell, C. A., Liu, C. & Sanchez, E. Rubbery solid electrolytes with dominant cationic transport and high ambient conductivity. Nature 362, 137–139 (1993).
Alarco, P. J., Abu-Lebdeh, Y., Abouimrane, A. & Armand, M. The plastic-crystalline phase of succinonitrile as a universal matrix for solid-state ionic conductors. Nat. Mater. 3, 476–481 (2004).
Croce, F., Appetecchi, G. B., Persi, L. & Scrosati, B. Nanocomposite polymer electrolytes for lithium batteries. Nature 394, 456–458 (1998).
Wang, Y. et al. Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways. Nat. Mater. 20, 1255–1263 (2021).
Khurana, R., Schaefer, J. L., Archer, L. A. & Coates, G. W. Suppression of lithium dendrite growth using cross-linked polyethylene/poly(ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries. J. Am. Chem. Soc. 136, 7395–7402 (2014).
Hu, P. et al. Progress in nitrile-based polymer electrolytes for high performance lithium batteries. J. Mater. Chem. A 4, 10070–10083 (2016).
Wang, C. et al. High polymerization conversion and stable high-voltage chemistry underpinning an in situ formed solid electrolyte. Chem. Mater. 32, 9167–9175 (2020).
Li, S. et al. A superionic conductive, electrochemically stable dual-salt polymer electrolyte. Joule 2, 1838–1856 (2018).
Lin, D. et al. A silica-aerogel-reinforced composite polymer electrolyte with high ionic conductivity and high modulus. Adv. Mater. 30, e1802661 (2018).
Fang, C. et al. Quantifying inactive lithium in lithium metal batteries. Nature 572, 511–515 (2019).
Ju, Z. et al. Biomacromolecules enabled dendrite-free lithium metal battery and its origin revealed by cryo-electron microscopy. Nat. Commun. 11, 488 (2020).
Li, Y. et al. Atomic structure of sensitive battery materials and interfaces revealed by cryo-electron microscopy. Science 358, 506–510 (2017).
Liu, Y. et al. Visualizing the sensitive lithium with atomic precision: cryogenic electron microscopy for batteries. Acc. Chem. Res. 54, 2088–2099 (2021).
Liu, Y. et al. Self-assembled monolayers direct a LiF-rich interphase toward long-life lithium metal batteries. Science 375, 739–745 (2022).
Sheng, O. et al. In situ construction of a LiF-enriched interface for stable all-solid-state batteries and its origin revealed by cryo-TEM. Adv. Mater. 32, 2000223 (2020).
Zachman, M. J., Tu, Z., Choudhury, S., Archer, L. A. & Kourkoutis, L. F. Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries. Nature 560, 345–349 (2018).
Zhang, Z. et al. Capturing the swelling of solid-electrolyte interphase in lithium metal batteries. Science 375, 66–70 (2022).
Xu, Y. et al. Atomic to nanoscale origin of vinylene carbonate enhanced cycling stability of lithium metal anode revealed by cryo-transmission electron microscopy. Nano Lett. 20, 418–425 (2020).
Zhang, X.-Q., Cheng X.-B, Chen, X., Yan, C. & Zhang, Q. Fluoroethylene carbonate additives to render uniform Li deposits in lithium metal batteries. Adv. Funct. Mater 27, 1605989 (2017).
Philippe, B. et al. Photoelectron spectroscopy for lithium battery interface studies. J. Electrochem. Soc. 163, A178–A191 (2015).
Ding, J. F. et al. Non-solvating and low-dielectricity cosolvent for anion-derived solid electrolyte interphases in lithium metal batteries. Angew. Chem. Int. Ed. Engl. 60, 11442–11447 (2021).
Han, L. et al. Modulating single-atom palladium sites with copper for enhanced ambient ammonia electrosynthesis. Angew. Chem. Int. Ed. Engl. 60, 345–350 (2021).
Xu, C. et al. Interface layer formation in solid polymer electrolyte lithium batteries: an XPS study. J. Mater. Chem. A 2, 7256–7264 (2014).
Xu, H. et al. High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide). Proc. Natl Acad. Sci. USA 116, 18815–18821 (2019).
Farhat, D. et al. Towards high-voltage Li-ion batteries: reversible cycling of graphite anodes and Li-ion batteries in adiponitrile-based electrolytes. Electrochim. Acta 281, 299–311 (2018).
Adams, B. D., Zheng, J., Ren, X., Xu, W. & Zhang, J. G. Accurate determination of Coulombic efficiency for lithium metal anodes and lithium metal batteries. Adv. Energy Mater. 8, 1702097 (2018).
Deng, T. et al. In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries. Chem 7, 3052–3068 (2021).
Lee, Y.-G. et al. High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes. Nat. Energy 5, 299–308 (2020).
Ye, L. & Li, X. A dynamic stability design strategy for lithium metal solid state batteries. Nature 593, 218–222 (2021).
Han, X. et al. Negating interfacial impedance in garnet-based solid-state Li metal batteries. Nat. Mater. 16, 572–579 (2017).
Gadim, T. D. et al. Nanostructured bacterial cellulose-poly(4-styrene sulfonic acid) composite membranes with high storage modulus and protonic conductivity. ACS Appl. Mater. Interfaces 6, 7864–7875 (2014).
Ma, J. et al. A strategy to make high voltage LiCoO2 compatible with polyethylene oxide electrolyte in all-solid-state lithium ion batteries. J. Electrochem. Soc. 164, A3454–A3461 (2017).
Chen, R. et al. An investigation of functionalized electrolyte using succinonitrile additive for high voltage lithium-ion batteries. J. Power Sources 306, 70–77 (2016).
Evans, J., Vincent, C. A. & Bruce, P. G. Electrochemical measurement of transference numbers in polymer electrolytes. Polymer 28, 2324–2328 (1987).
